Barca found themselves ahead in the first minute when Raphinha was sent bearing down on goal before smashing past goalkeeper Manuel Neuer. Kane had the ball in the net less than 10 minutes later, but it was ruled out for offside.
That was just a brief setback for the English forward, though, as he was soon found in the Barca again as he met Serge Gnabry's cross and pulled off an acrobatic finish to level matters.