With the two teams still testing each other, Samkelo Zwane picked his Kaizer Chiefs teammate Naledi Hlongwane who smartly beat Elvis Chipezeze to give the All-Stars team the lead after 11 minutes.
Zwane then got his name on the scoresheet 10 minutes later when he received a neat pass from Ashley du Preez.
Hlongwane was back again with a low drive that beat Chipezeze in 23 minutes after being set up by Orlando Pirates defender Mbekezeli Mbokazi.
It ended 3-0 in favour of the All-Stars team on the day as Orlando Pirates coach Jose Riveiro masterminded a second successive Carling Cup win.