Barcelona, who top the league by three points from Real Madrid and five from Atletico Madrid, host Celta Vigo.
Kick-off is Saturday 5 December at the Camp Nou (9:00pm Central European Time).
According to the newspaper "Mundo Deportivo", that was the only possible date for the Catalans and the Galicians to meet, with too little room between Barcelona's clash with Atletico Madrid on Wednesday 2 December and the Champions League trip to Manchester City on Tuesday 8 December.
Elsewhere in the same round, Athletic Bilbao face Real Madrid on Sunday 6 December at San Mames. Madrid come in off a trip to the Anoeta (Real Sociedad) on Wednesday 2 December, then travel to Arsenal on Wednesday 9 December in the Champions League.
Atletico Madrid, meanwhile, host Real Betis on Sunday 6 December in an eagerly awaited tie at the Wanda Metropolitano, before Diego Simeone's side travel to Stuttgart on Wednesday 9 December
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in the Champions League. Manuel Pellegrini's Real Betis take on Como and their man Cesc Fabregas at La Cartuja the same day.
The international break: Barcelona's nightmare
This international break has been anything but comfortable for Barcelona. Hansi Flick had hoped to rest some of his key men ahead of a hectic end to the year. Instead, the German now has two fresh problems on his hands.
The first, according to the website "Foot Mercato", concerns Frenkie de Jong. Back from a long absence after the knee injury he suffered at the World Cup, the Dutch midfielder had to leave the national team camp.
Xavi Hernandez, the Netherlands coach, spoke only of back pain after the win over Greece. The Dutch federation then confirmed their player would not travel to Berlin for Monday's meeting with Germany. According to the newspaper "AS", the real issue is thigh pain.
Uncertainty hangs over Barcelona. The newspaper "Sport" reports that De Jong will be assessed next Monday by the Catalan club's medical staff, who will then decide whether further tests are needed.
De Jong to miss the Villarreal match
One thing is clear already: the Dutchman will rest this week, and taking any part in the game against Villarreal at the Camp Nou looks all but impossible.
A knock in such a sensitive area has Barcelona treading carefully. The former Ajax man has only just come back from injury, and Flick plainly has no intention of gambling with his midfielder.
Barcelona do not understand Brazil's decision
Raphinha's situation, meanwhile, is stirring tension in Catalonia. Sent off alongside Carlo Ancelotti during Brazil's 3-2 defeat to Japan after fierce protests over Japan's late goal, the Barcelona forward picks up an automatic ban for Brazil's second friendly, against Singapore on Tuesday.
Barcelona would happily see their man back early to prepare properly for the restart. The Brazilian Football Federation had other ideas.
Rodrigo Caetano, general executive coordinator of Brazil's men's national teams, explained: "Raphinha will stay. In principle, he will stay with us... His departure would not make sense, as he is one of our leaders".

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