Shortly after Dayot Upamecano opened the scoring just four minutes into the clash in Dortmund, Kane doubled their advantage. He added a third after 72 minutes and then rounded off the scoring in stoppage time.
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THE BIGGER PICTURE
The treble is Kane's second in a row for Bayern, having fired in three when they ran out 8-0 winners against Darmstadt last week, including an effort from his own half.
He is also the only Bundesliga player in history to score 15 goals in his first 10 matches.
WHAT THEY SAID
Kane's growing collection of match balls after his latest hat-trick prompted a joke from co-star Muller, who came up to him after the game and said: "Your hotel room gets smaller and smaller now, huh?"
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WHAT HAPPENS NEXT?
Kane will hope to continue his goalscoring form on Wednesday when his side face Galatasaray in the Champions League.