The Brazilian made his return from an injury lay-off to hit four goals as the Paris outfit rolled to an 8-0 win in Ligue 1 action.
PSG were comfortably ahead by the time Neymar got rolling, with Angel Di Maria's double and an Edinson Cavani strike pushing the league leaders into a 3-0 lead after 21 minutes.
But once the Brazilian got it going, there was no stopping him.
A brilliant free kick from the record signing made it 4-0 just before half-time.
After adding another in the 57th minute, the 25-year-old posted his best of the night in the 73rd to round out his hat-trick.
Neymar supplied the assists for Kylian Mbappe to make it 7-0 and finished off the scoring with a penalty late on.
42' - ⚽️— Goal (@goal) January 17, 2018
57' - ⚽️
73' - ⚽️
83' - ⚽️
Neymar put on a show as he scored four goals in PSG's 8-0 win over Dijon. 😎 pic.twitter.com/WaotwSzSRO
On a night when Cavani equalled Zlatan Ibrahimovic's record of 156 goals for Paris Saint-Germain in all competitions , it was Neymar's return to top form that stole the show.
In fact, the became the first player to be involved in six goals in Ligue one since Opta started collecting data on the French top flight, having also assisted on Di Maria's second.
6 - @neymarjr is the 1st player involved in 6 goals in a single Ligue 1 game since Opta started to collect the data for Ligue 1 in 2006/07 (4 goals, 2 assists). Unreal. @PSG_English pic.twitter.com/XdmmCZGMrH— OptaJean (@OptaJean) January 17, 2018
PSG are now 11 points clear of Lyon at the top of the Ligue 1 table.