PSG have scored 53 times in their previous 18 games in this competition (2.9 per match) and with Napoli adopting an attacking approach too, this should be an exciting 90 minutes.
The firepower on show in Paris makes the game a natural choice for the neutral but the high goal expectancy also lends itself to closer investigation of the anytime scorer market.
Neymar (10/11) leads the way and his record to date deserves the respect he's afforded by the odds compilers.
The former Barcelona man needs just one more goal to become the outright top scoring Brazilian in the competition's history, overtaking Kaka once he achieves the 30-goal milestone.
Edinson Cavani (Evens) lines up against his former club for the first time since leaving Naples in 2013. He plundered 104 goals in 138 games for the Italian side and has five more in seven league games this campaign and another in Europe.
A better choice for this game though, looks to be Kylian Mbappe at Evens (2.0) with 888Sport.
The 19-year-old World Cup winner has started the season in blistering form. Mbappe has nine goals in just six Ligue 1 appearances so far and has also found the net in both of PSG's Champions League ties so far including in the 3-2 defeat to Liverpool on matchday one.
While PSG boast a galaxy of attacking options it’s Mbappe that's shining brightest so far this term and the opportunity to get Evens (2.0) about him extending a scoring streak which has seen the Frenchman net in each of his last three club matches looks too good to pass up with 888Sport.