The match is the Three Lions' first since the World Cup, in which Kane finished as top goalscorer, scoring six times in his side's run to the semi-finals.
The Tottenham star is due to be presented with the Golden Boot trophy at Wembley before the game against Julen Lopetegui's side.
To mark the occasion, Nike have created some personalised footwear for the 25-year-old.
"Buzzing to wear these tomorrow night," Kane tweeted on Friday alongside a picture of his new boots, which contain the words 'Lane, Lion, Leader' on the inside. The word 'Lane' represents Kane's old home ground with Spurs, White Hart Lane, while the other terms are references to his international career with the Three Lions.