The German replaces Simon Mignolet in goal, with the speedster switching in for Alex Oxlade-Chamberlain.
Those are two of five changes Jurgen Klopp has made to the starting XI with a trip to Burnley to come on Monday.
Dejan Lovren comes in for Ragnar Klavan at the heart of defence, Joe Gomez is at right-back with Trent Alexander-Arnold moving to the bench and James Milner replaces Gini Wijnaldum in the centre of the park.
Liverpool starting XI: Karius, Gomez, Matip, Lovren, Robertson, Can, Milner, Coutinho, Mane, Salah, Firmino
Liverpool subs: Mignolet, Klavan, Alexander-Arnold, Wijnaldum, Lallana, Oxlade-Chamberlain, Solanke