Tite's men qualified for the tournament in stunning fashion and are just behind holders Germany in the outright market to lift the trophy once more at 5/1 (6.0).
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Brazil will be missing Neymar, who is recovering from injury. Tite could give a debut to Real Sociedad striker Willian Jose, whose 13 La Liga goals this term have rewarded him with his first international call-up.
Russia's squad, meanwhile, is made up almost entirely of home-based players, although Villarreal winger Denis Cherychev could be in-line to make his first international appearance since 2015.
La Canarinha to warm up with few problems
The visitors will be hoping that this will not be their only visit to the Luzhniki stadium this summer, with the ground also hosting the World Cup final on 15 July.
Friday's game will be useful preparation ahead of the tournament for a Brazil side who boast an extraordinary record in friendlies.
Indeed, the five-time World Cup winners have won 25 of their last 27 friendlies and another victory is surely on the cards.
Preview and predictions
Brazil to win and under 3.5 goals is priced at 23/20 (2.15) and looks a shrewd way to back a victory for Tite's side.
The game should see the manager experiment a little, meaning that backing a low-scoring win for Brazil against a side that is likely to set up in extremely defensive fashion is a logical selection.