Group B looks well poised ahead of the final round of matches on Monday and every team will feel they still have a decent chance of making it through to the knockout stages. With both games being played at the same time it promises to be an intriguing evening of action around France.
To add to the excitement, anyone yet to open a Paddy Power account can take up an enhanced price on England, Wales or the home nations double when signing up.
Taking advantage of these odds is simple; just register through the corresponding links, back your chosen outcome at the usual price shown on site and if the bet wins, the returns will be topped up at the final whistle.
The feel-good factor around the England camp is tangible after their late winner which denied Wales a share of the points in Lille on Thursday. The introduction of Jamie Vardy and Daniel Sturridge proved pivotal and the prospect of the two frontmen starting against Slovakia is certainly an exciting one for backers of the Three Lions.
Topping the group hands England a significant advantage and - with Wales picking up a victory in their opening game of the tournament - Roy Hodgson will be acutely aware that nothing less than a victory will guarantee safe passage into the knockout stages in top spot. The quotes of 5/1 (6.0) on England make plenty of appeal considering their usual odds of 3/4 (1.75) and the need to extend their winning run.
Russia's ageing backline was brutally exposed by Slovakia on matchday two and the last man Leonid Slutsky's side will want to deal with is an in-form Gareth Bale, who has proved as deadly from set pieces as he has been from open play so far this tournament. The odds of 2/1 (3.0) about a Wales win make plenty of appeal given what we've seen so far but the opportunity to back them at 10/1 (11.0) should prove extremely popular.
Chris Coleman's side will need to deal with the cruel blow of England's late winner in Lille but they undoubtedly have the weapons to hurt a team who have been hampered by injuries in the run up to their campaign. What's more, their need to push for a result will surely play into Wales' hands as they thrive in breaking forward at speed, something they should have plenty of opportunity to do given the situation surrounding this clash.
Given the cases made for backing either England or Wales at vastly improved odds compared to the usual prices available, the opportunity to back the double at quotes of 16/1 (17.0) looks a great opportunity for those looking to maximise the potential to grow their new account balance.
Currently a 9/2 (5.50) chance at the best prices available at the time of writing, punters who believe it is set to be a good night for the two home nations in action can back this double at over three times the usual odds when opening a new Paddy Power account.