They will now face Manchester United in the knockout stages in what is set to be a mouthwatering clash between the two giants.
One man who will be on the spotlight for this game will be PSG's Brazilian forward Neymar who is expected to lead the Parisiens'charge in Europe.
The Brazilian already has five goals from six appearances in the group stages, in addition to two assists. He has also created four big chances and will be a threat to the fragile Manchester United defence.
In the process of the group stages, he also became the highest scoring Brazilian in the competition, surpassing Kaka's record.
Watch all his best plays in Europe so far here.