| 1 Davide Bassi | Goalkeeper | 10 Ighli Vannucchi | Midfielder | |
| 23 Renato Dossena | Goalkeeper | 17 Gianluca Musacci | Midfielder | |
| 27 Alberto Pelagotti | Goalkeeper | 26 Marco Mancosu | Midfielder | |
| 2 Andrea Cupi | Defender | 28 Samuele Pizza | Midfielder | |
| 3 Adam Kokoszka | Defender | 36 Nikola Gulan | Midfielder | |
| 4 Vittorio Tosto | Goalkeeper | 53 Pietro De Giorgio | Midfielder | |
| 9 Angelo Antonazzo | Defender | 7 Eder | Striker | |
| 16 Gabriele Angella | Defender | 11 Luca Saudati | Striker | |
| 19 Simone Iacoponi | Defender | 20 Christian Cesaretti | Striker | |
| 21 Lorenzo Stovini | Defender | 31 Diego Fabbrini | Striker | |
| 22 Alessandro Vinci | Defender | 34 Christian Pasquato | Midfielder | |
| 25 Daniele Mori | Defender | 77 Matteo Negrini | Striker | |
| 6 Mirko Valdifiori | Midfielder | 99 Claudio Coralli | Striker | |
| 8 Francesco Marianini | Midfielder | - Salvatore Campilongo | Manager/Coach |
| Player | Goals | Penalties | ||
|---|---|---|---|---|
 | Eder Empoli | A | 10 | 5 |
 | C. Coralli Empoli | A | 6 | 0 |
 | F. Marianini Empoli | C | 4 | 0 |
 | A. Antonazzo Empoli | D | 2 | 0 |
 | M. Valdifiori Empoli | C | 1 | 0 |
| Player |
To |
From |
|
|---|---|---|---|
 | S. Caturano Striker | Esperia Viareggio | Empoli |
 | L. Stovini Defender | Empoli | Unattached |
 | N. Pozzi Striker | Sampdoria | Empoli |
| A. Antonazzo Defender | Empoli | Chievo |
 | F. Piccolo Defender | Chievo | Empoli |
 | F. Lodi Midfielder | Udinese | Empoli |
 | D. Moro Midfielder | Livorno | Empoli |
| Empoli - Ancona | 2/12/10 |
| Frosinone - Empoli | 2/20/10 |
| Empoli - Modena | 2/27/10 |
| Cittadella - Empoli | 3/6/10 |
| Empoli - Gallipoli | 3/13/10 |
| Triestina - Empoli | 3/20/10 |
| Empoli - Mantova | 3/23/10 |
| Ascoli - Empoli | 3/27/10 |
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