The midfielder says Louis van Gaal's men are focused on qualifying for the tournament this season
After finishing seventh in the Premier League last season, United are embarking on a campaign without continental football for the first time since 1989-90.
And Herrera, who saw a move to United fall through in 2013, insists Louis van Gaal's squad are determined to make up for last season.
"I would never have left Athletic if it hadn't been for a club like United," Herrera told The Guardian. "United is an opportunity you can't turn down.
"I left a different, unique club, with a special philosophy and incredible people.
"It's a club that few of us have had the privilege of playing for and, who knows, but for United I might have been there 10 years.
"But this is the biggest club in England, a new project, new players and a new coach.
"[There is] desire too: it's been 25 years and the players are conscious of that. They're determined to put United back where it belongs."
Herrera is set to make his Premier League debut against Swansea City at Old Trafford on Saturday.