The Brazilian misses out after picking up a fifth yellow card in the previous clash with Rayo Vallecano, meaning that only Lionel Messi and Luis Suarez will take the field out of the Blaugrana's famous trio.
In midfield, Andres Iniesta begins the match on the bench, with Luis Enrique selecting Arda Turan alongside Ivan Rakitic and Sergio Busquets.
Eibar, meanwhile, have collapsed in the second half of the season, with six defeats from their last seven, and face an uphill challenge - having never taken a point off Barcelona since promotion in 2014.
EIBAR: Riesgo, Capa, Pantic, Rami, Juncà, Adrián, Escalante, Dani García, Radosevic, Bastón, Enrich.
SUBS: Irureta, Antosegi, Inui, Hajrovic, Dos Santos, Luna, Saul Berjon.
BARCELONA: Bravo; Alves, Piqué, Mascherano, Alba; Busquets, Arda, Rakitic; Messi, Suárez, Munir.
SUBS: Ter Stegen, Iniesta, Bartra, Sergi Roberto, Vidal, Vermaelen, Mathieu.