The Italian and Montenegrin will lead the frontline for the Serie A champions as they make their home bow in this season's Champions League
The duo will be tasked with firing the Serie A side - who have started their domestic campaign in superb form - to victory over the Ukrainian outfit in Turin.
Behind the pairing, the formidable midfield trio of Claudio Marchisio, Arturo Vidal and Andrea Pirlo are all present.
For Shakhtar Donetsk, Henrikh Mkhitaryan will be the main threat, supported by an able attacking trio of Luiz Adriano, Willian, and Alex Texeira.
Juventus: Buffon; Barzagli, Bonucci, Chiellini; Lichsteiner, Marchisio, Vidal, Pirlo, Asamoah; Matri, Vucinic
Shakhtar Donetsk: Pyatov; Srna, Rakitskiy, Kucher, Rat; Hubschman, Fernandinho; Alex Texeira, Willian, Luiz Adriano; Mkhitaryan