Bayern Munich, meanwhile, travel to newly-promoted side Greuther Furth on matchday one of the new season as they look to wrest back the title.
Schalke, who finished the 2011-12 campaign in third position, will have to deal with Hannover in their first match of the new season, while Champions League hopefuls Borussia Monchengladbach have been paired with Hoffenheim.
|Borussia Dortmund||Werder Bremen|
|Eintracht Frankfurt||Bayer Leverkusen|
|Greuther Furth||Bayern Munich|