The Brazilian is yet to extend his current deal at Camp Nou which has led to speculation surrounding his future while former Madrid defender Roberto Carlos has claimed he could persuade the 24-year-old to move to the Bernabeu.
The Madrid giants were interested in signing the attacker from former club Santos back in 2013, with Spanish press reported in January that Los Blancos are continuing their pursuit.
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However, club team-mate Pique is adamant the deal would never go through, stating via Periscope: “I’d bet an arm or a hand that Ney will never join Madrid.
“He likes Barcelona very much, he’s in love with the club and I think he’ll stay here for many years."