Brazil: Julio Cesar; Daniel Alves, Lucio, Thiago Silva, Andre Santos; Lucas Leiva, Ramires, Ganso; Robinho, Alexandre Pato, Neymar
The five-time World Cup winners are at full strength going into their opening Copa America 2011 game. Ganso looks set to start in midfield with Elano likely to be on the bench while Alexandre Pato will line up alongside Robinho and Neymar to form a potentially devastating three-pronged attack.
Cesar Farias' side could be one of the surprise outfits of the tournament, thanks to a number of exciting youngsters. Rosales, Rincon, Rondon and Orozco are all expected to make an impact on the tournament and could be the nation's dangermen versus Brazil.
DID YOU KNOW?
Brazil have won the Copa America eight times, putting them behind both Argentina and Uruguay who have won the tournament on 14 occasions each.
Ganso looks set to be a key player for Mano Menezes' team despite making only one previous appearance for the national side in a friendly against the U.S in August 2010.
Brazil are the current reigning Copa America champions, defeating fierce rivals Argentina 3-0 in Venezuela four years ago.
The last time these two sides met, Brazil could only manage a 0-0 draw at home in a World Cup 2010 qualification game.
Brazilian captain Lucio is set to win his 100th cap for the national team against Venezuela, with the Inter centre-back being the fourth most capped player for the national side.
Venezuela have never won the Copa America with their best showing coming in the first time the nation competed, back in 1967.
Veteran defender Juan Manuel Rey is the nation's most capped international, picking up a total of 111 caps so far after making his debut in a World Cup qualifier against Bolivia in 1997.
Venezuela are the only South American nation to have never qualified for a World Cup.
The country's coach, Cesar Farias previously coached Venezuela's under-20s at the 2009 under-20 World Cup, and took a squad including the likes of Salomon Rondon and Yohandry Orozco to the last 16 of the competition.
Atlante striker Giancarlo Maldonado is Venezuela's top goalscorer, netting 20 times in a total of 55 appearances.
Follow Goal.com on. Get the latest football news direct... Check out Goal.com's page; be part of the best football fan community in the world!
Sign up with William Hill for a free bet up to £25
Sign up with bet365 for a 100% deposit bonus up to £200
The elegant playmaker is earmarked as a future star of the Brazilian national side and will be keen to showcase his talents during the Copa America tournament. His vision and passing ability will be vital for Brazil.
The marauding right-back could be key to Venezuela's attacking threat against Brazil with the Twente player sure to test Andre Santos down their opposition's left flank. Rosales is the only Venezuelan player in history to score in the Champions League.
With Brazil's vast array of attacking talent, it's difficult to look beyond Mano Menezes' men for this one. Venezuela have some lively attackers at their disposal but their defensive vulnerabilities are sure to let them down against the giants of international football.