The Azzurri No.1 ensured his side emerged with a clean sheet as he produced several fine stops to deny Napoli.
He rarely put a foot wrong in the Juventus defence and allowed Higuain very little time on the ball as well as making a number of important tackles and interceptions.
The centre-back produced some wonderful Pirlo-esque passes to stretch the Napoli defence and was denied a goal by a fantastic reflex save from Reina.
Produced a fine defensive display to contain Higuain but was dismissed late on for a second bookable offence.
A simply magnificent performance: He pulled the strings effortlessly in midfield and scored with a sublime trademark free kick.
The Ghanaian wideman missed a good opportunity in the first half although he proved solid in defence, rarely leaving his wing exposed.
Combined excellently with Vidal and looked threatening when coming forward down the right, delivering a number of testing crosses into the box.
Showed just why is he is one of the greatest talents in Europe by firing an unstoppable shot past Reina to wrap up the points.
The Chilean epitomised his side's spirit with a tireless box-to-box performance. Broke up play effectively and provided the assist for Pogba's stunner.
The Argentine striker continues to impress in the Bianconeri jersey and although he did not get on the scoresheet, he was a constant thorn in the Partenopei defence with his intelligent movement and abillity to find a team-mate in tight situations.
After rescuing a point with a late header against Real Madrid in midweek, the Spanish striker got on the scoresheet again when he reacted well to poke the ball home at the back post.
Kept his side in the contest by making two wonderful saves to deny Bonucci and Llorente in the first half but was helpless to prevent any of the goals.
The Colombian got into some promising advanced positions down the left and was involved in the majority of his side's attacks.
The centre-back struggled to deal with Llorente's physical presence and was caught out on several occasions.
He produced some brave headers to deny the Juventus attack although lost the run of Llorente for the opening goal.
The right-back struggled to get forward to aid the attack although did a good job to restrict Asamoah's impact.
Helped keep things tidy in the midfield and offered good protection to the defence.
Battled bravely in the heart of midfield and was burdened with the task of stifling Tevez when the Argentine dropped deep, which he did to good effect.
The captain showed glimpses of his quality with some clever through balls but did not influence the game as much as he would have liked and missed a good chance to level the scores.
He was Napoli's brightest spark and caused Barzagli problems when cutting in from the left. The future looks bright for the Italy international who forced his international colleague Buffon into several smart saves.
Aside from one good opening he fashioned for himself in the first half, Higuain was given little space by the Juventus defence and was well marshaled throughout.
A rather anonymous performance from the former Real Madrid attacker who struggled to get on the ball and show his quality.