The current Selecao manager was in the running to take over from Sven-Goran Eriksson in 2006 but ruled himself out of the running because of his contract with Portugal.
The 64-year-old is in his second spell in charge of the Selecao, the Three Lions' Wembley opponents on Wednesday evening, and was approached by the Football Association six-and-a-half years ago to replace Sven-Goran Eriksson.
After the FA offered a long-term deal to the Brazilian prior to World Cup 2006, Scolari U-turned, citing the intrusive nature of the British press as his reason for pulling out of the running.
Yet he spoke in a Tuesday press conference of the “hurt” he suffered, despite admitting that he did not want to break his contract with Portugal - England's eventual conquerors at the tournament in Germany.
“Of course it hurts,” he said. “It hurts a lot, because I would have loved to have been manager of the England national team. Who wouldn’t?
“When I was invited to be national coach of England, when we sat together at that time, I still had a contract with Portugal.
“I wasn’t willing to break that contract – it was my duty to fulfill it. Imagine in 2006 if we had played together and I already had a contract with England!
“But England are a wonderful team and I hope I will have the opportunity to talk to Lampard and Ashley Cole at the game, to wish them the best. You never know what might happen one day.”
Follow GOAL.COM on