The 50-year-old, who had been working as part of Frank de Boer's backroom staff at Ajax, has also confirmed his dream of reuniting with his former club boss.
"I've always had the intention of doing something with Louis [van Gaal] someday," he told ad.nl. "If it is then possible at the highest level, in the Dutch national team, that's incredible."
Van Gaal replaced previous boss Bert van Marwijk on Friday as the national team coach, after the Oranje's disastrous Euro 2012 campaign ended with no wins out of three.
Blind played 42 games for Netherlands between 1986 and 1996, scoring one goal.