The Colombia international only arrived in the Spanish capital this summer, having joined the reigning European champions from Monaco for a reported €80 million.
However, James says that he has little trouble settling into his new surroundings at the Santiago Bernabeu, thanks in no small part to the Ballon d'Or winner.
“I’ve formed a good relationship with him and I hope that we can be together for a long time,” declared the 23-year-old.
"But all of the players are very humble, which is why they are there and why they are great players."
James, of course, was signed on the back of his sensational exploits at this summer's World Cup, with the 23-year-old bagging the Golden Boot after netting six times in just five games.
He thrived in an attacking midfield role for Jose Pekerman's side but it remains to be seen whether he will be allowed to occupy his preferred position for Madrid.
James, though, insists that he does not mind where he is deployed by Carlo Ancelotti, insisting that he is willing to be fielded in a more withdrawn role if needs be.
"I'll play where the coach wants and I'll be happy there," the former Porto man stated.
James has scored one goal in his five competitive outings for Madrid so far this season.