Southampton midfielder Adam Lallana and Tottenham's Jake Livermore are also brought in for the game on Tuesday as the Arsenal man is withdrawn and Daniel Sturridge is a doubt
Roy Hodgson's men suffered a set-back when Daniel Sturridge (stomach cramps) and Theo Walcott (illness) both missed training on Monday.
The Arsenal man has returned to the north London club having been ruled out of Tuesday's clash with Oleg Blokhin's side, however the Three Lions' medical team are hopeful that the Chelsea forward will recover in time.
|11/4||Raheem Sterling is 11/4 with Bet365 to score anytime in England v Ukraine
With Andy Carroll also having missed the 5-0 win over Moldova, and Wayne Rooney currently sidelined, the England boss has decided to bolster his attacking options with the Reds' youngster.
Sterling has only recently broken into the Merseyside outfit's first team, after impressing for the youth and reserve sides last season and pre-season this term, but has already shown glimpses of quality in the Premier League.
The news comes just after the Jamaica national team coach, Theodore Whitmore, expressed interest in tempting the teenager, who was born in Kingston, into representing his country of birth.
The former West Brom manager has also handed call-ups to newly-promoted Southampton's playmaker Adam Lallana and Tottenham midfielder Jake Livermore as extra cover after losing five players from his original squad.