Del Piero was available on a free after Juventus opted not to renew his expiring contract this summer, and the former Italy international will now continue his career in Australia.
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Sydney FC already announced on Friday that Del Piero had agreed to finalise a deal with the Sky Blues, with CEO Tony Pignata travelling to Italy this week to complete the move.
Liverpool made a late swoop for the 37-year-old on Tuesday, but their attempt has proven unfruitful as Del Piero has opted to join Sydney instead, and has inked a two-year deal with his new club.
A press conference has been scheduled, where Del Piero is expected to confirm his decision to leave Europe for an adventure at Sydney FC.